Journal
RSC ADVANCES
Volume 7, Issue 18, Pages 10865-10868Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra26826a
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Funding
- National Research Foundation - MSIP [2015R1A2A1A15055347]
- National Research Foundation of Korea [2015R1A2A1A15055347] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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We developed two electrochemiluminescent probes (1, 2) for sulfide (S2-), based on cyclometalated Ir(III) complexes. Addition of sulfide anions greatly increased the ECL signal of probes by cleaving a PET quencher moiety from probe ligands. Probe 2 showed a high turn-on ratio of ECL and good selectivity for sulfide anions over various anions and biothiols.
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