Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 23, Issue 31, Pages 7444-7447Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201701589
Keywords
acyl radicals; carboxylic acids; cascade transformation; multicomponent reactions; photoredox catalysis
Categories
Funding
- European Commission [660668]
- Marie Curie Actions (MSCA) [660668] Funding Source: Marie Curie Actions (MSCA)
Ask authors/readers for more resources
Visible-light photoredox catalysis has been utilized in a new multicomponent reaction forming beta-functionalized delta-diketones under mild conditions in an operationally convenient manner. Single-electron reduction of in situ generated carboxylic acid derivatives forms acyl radicals that react further via 1,2-acylalkylation of olefins in an intermolecular, three-components cascade reaction, giving valuable synthetic entities from readily available starting materials. A diverse set of substrates has been used, demonstrating robust methodology with broad substrate scope.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available