Journal
CHEMISTRY LETTERS
Volume 46, Issue 2, Pages 260-262Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.161019
Keywords
Porphycene; Intramolecular oxidative coupling; Hypervalent iodine(III)
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Funding
- Japan Science and Technology Agency (JST)
- JSPS KAKENHI [JP16H04119, JP16H01035, JP15H00757]
- Grants-in-Aid for Scientific Research [16H01035, 16H04119, 15H00757] Funding Source: KAKEN
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meso-Tetraalkylporphycenes were synthesized in a few steps using intramolecular oxidative coupling of the Z-isomer of 5,6dialkyldipyrroethenes. The use of a hypervalent iodine(III) reagent, namely phenyliodine(III) bis(trifluoroacetate), is essential for performing these reactions.
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