Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 46, Pages 6207-6210Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc03368k
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- Netherlands Organisation for Scientific Research (NWO) through a VICI grant [724.014.003]
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The vanadium-dependent chloroperoxidase from Curvularia inaequalis is a stable and efficient biocatalyst for the hydroxyhalogenation of a broad range of alkenes into halohydrins. Up to 1 200 000 TON with 69 s(-1) TOF were observed for the biocatalyst. A bienzymatic cascade to yield epoxides as reaction products is presented.
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