Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 46, Pages 6219-6222Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc02484c
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Funding
- National Natural Science Foundation of China [21327010, 21372199, 21502168]
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Hemin-catalyzed competing routes of [1,2]-Stevens and Sommelet-Hauser rearrangements of benzyl sulfonium ylides through an iron porphyrin carbenoid were established. These rearrangements can be controlled by the electronic property of the substituents on the benzyl group together with solvent effects. Electron-donating or weak electron-withdrawing groups lead to the [1,2]-Stevens rearrangement, whereas strong electron-withdrawing groups at the para-position favor the latter pathway under aqueous conditions.
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