Journal
DALTON TRANSACTIONS
Volume 46, Issue 19, Pages 6183-6186Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7dt01094j
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- Deutsche Forschungsgemeinschaft through the International Research Training Group Selectivity in Chemoand Biocatalysis
- Alexander von Humboldt Foundation
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The zinc hydridotriphenylborates [(L) Zn(TMDS)][HBPh3] and [(L)ZnX][HBPh3] (L = Me(4)TACD, Me-4[12] aneN(4); TMDS = N(SiHMe2)(2); X = Cl, Br, I) were synthesized by BPh3-mediated beta-SiH abstraction and salt metathesis with KHBPh3, respectively. CO2 is rapidly inserted into the B-H bonds. [(L) Zn(TMDS)][HBPh3] catalyzes the hydroboration of polar substrates including CO2.
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