Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 25, Pages 7209-7212Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201702950
Keywords
electrostatic interactions; fluorine; F-pi interactions; supramolecular chemistry; pi interactions
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Funding
- National Science Foundation [CHE 1310139]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1310139] Funding Source: National Science Foundation
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A series of N-arylimide molecular balances were designed to study and measure fluorine-aromatic (F-pi) interactions. Fluorine substituents gave rise to increasingly more stabilizing interactions with more electron-deficient aromatic surfaces. The attractive F-pi interaction is electrostatically driven and is stronger than other halogen-pi interactions.
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