Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 27, Pages 7826-7830Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201703334
Keywords
density functional calculations; small ring systems; photocatalysis; reaction mechanisms; ring expansion
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Funding
- Spanish Government [CTQ2015-64561-R, CTQ2014-59544-P]
- European Research Council (ERC-CG) [647550]
- UAM
- MINECO
- ICREA
- European Research Council (ERC) [647550] Funding Source: European Research Council (ERC)
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Described herein is a new visible-light photocatalytic strategy for the synthesis of enantioenriched dihydrofurans and cyclopentenes by an intramolecular nitro cyclopropane ring expansion reaction. Mechanistic studies and DFT calculations are used to elucidate the key factors in this new ring expansion reaction, and the need for the nitro group on the cyclopropane.
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