Journal
DALTON TRANSACTIONS
Volume 46, Issue 24, Pages 7750-7757Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7dt01549f
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Funding
- MINECO
- FEDER [CTQ2015-70231-P]
- Principado de Asturias [FC-15GRUPIN14-103]
- Ministerio de Educacion for an FPU predoctoral fellowship
- Natural Sciences and Engineering Research Council
- CRC programme
- Mount Allison University
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The first examples for the rhenium-catalysed hydroboration of aldehydes, ketones and aldimines, including heteroaromatic quinoline, are reported herein. Reactions are remarkably chemoselective and tolerant of several functional groups. A wide array of rhenium complexes were efficient pre-catalysts for these hydroborations, including new low-valent complexes of the formula [Re(N-N)(CO)(3)(L)] X (N-N = bipy derivative, L = labile ligand/solvent, and X = [BAr4F]-and [B(3,5-di-tBu-cat)(2)](-)), which have been characterized fully including an X-ray diffraction study for [Re(bipy)(CO) 3(quin)][BArF (4)] (2). A new silver spiroboronate ester Ag[B(3,5-di-tBu-cat)(2)](NCCH3)(3) (3) was prepared and characterized fully, including an X-ray diffraction study, and used to make one of the new rhenium complexes.
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