Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 48, Pages 6401-6404Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc01932g
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Funding
- Ministry of Education, Culture, Sports, Science and Technology of Japan
- Grants-in-Aid for Scientific Research [15K05502] Funding Source: KAKEN
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Reductive cross-coupling of aryl halides with ubiquitous alkyl tosylates was developed using a combination of nickel and vitamin B-12 (VB12: cyanocobalamin) catalysts. The tosylate was activated by reduced VB12 to form alkyl cobalt(III), which served as a good alkylating agent for aryl-nickel species, leading to C(sp(3))- C(sp(2)) bond formation.
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