4.6 Review

Equilibrium gels of limited valence colloids

Journal

CURRENT OPINION IN COLLOID & INTERFACE SCIENCE
Volume 30, Issue -, Pages 90-96

Publisher

ELSEVIER SCIENCE LONDON
DOI: 10.1016/j.cocis.2017.06.001

Keywords

Equilibrium gels; Depletion gels; Colloidal gels; DNA constructs; DNA nanostars; Patchy particles; Limited valence

Funding

  1. ETN-COLLDENSE [642774]
  2. ERC MIMIC [681597]
  3. European Research Council (ERC) [681597] Funding Source: European Research Council (ERC)

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Gels are low-packing arrested states of matter which are able to support stress. On cooling, limited valence colloidal particles form open networks stabilized by the progressive increase of the interparticle bond lifetime. These gels, named equilibrium gels, are the focus of this review article. Differently from other types of colloidal gels, equilibrium gels do not require an underlying phase separation to form. Oppositely, they form in a region of densities deprived of thermodynamic instabilities. Limited valence equilibrium gels neither coarsen nor age with time. (C) 2017 Elsevier Ltd. All rights reserved.

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