Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 27, Pages 7975-7979Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201703324
Keywords
boron heterocycles; borylenes; density functional calculations; iminoboranes; nitrenes
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Funding
- Deutsche Forschungsgemeinschaft
- Germany-India DAAD-DST Personnel Exchange Programme
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Although the metathesis of metal-boron double bonds with elemental chalcogenides is an established process, no similar reactivity has been observed with element-nitrogen bonds. Such a reaction would provide a new route to iminoborane compounds (RB equivalent to NR'), which have recently experienced renewed synthetic interest. Herein, we present the first observation of M=B/C=N metathesis reactions, which led to the isolation of a stable iminoborane in addition to further iminoborane cycloaddition products.
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