Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 23, Issue 34, Pages 8176-8179Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201702040
Keywords
catalyst-free; photosynthesis; radicals; silyl enolate; sulfur dioxide
Categories
Funding
- National Natural Science Foundation of China [21372046, 21532001]
Ask authors/readers for more resources
A N-radical-initiated cyclization involving the sulfonylation of unactivated alkenes through insertion of sulfur dioxide in the presence of visible light under catalyst-free conditions is accomplished. A range of sulfonated 3,4-dihydro-2H-pyrroles can be generated in good yields under photoinduced sulfonylative conditions. Additionally, the corresponding 2-(3,4-dihydro-2H-pyrrol-2-yl)methylsulfonyl-1-arylethanones can be easily converted to 3,4-dihydro-2H-1,4-thiazine 1,1-dioxides. This photoinduced transformation occurs efficiently at room temperature under catalyst-free conditions, and various functional groups can be tolerated. A tandem radical process is involved through the iminyl radical-mediated cyclization with the insertion of sulfur dioxide; this process shows high efficiency and good selectivity.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available