4.7 Article

High molecular weight poly(N-methyl-B-vinylazaborine) - a semi-inorganic B-N polystyrene analogue

Journal

CHEMICAL COMMUNICATIONS
Volume 53, Issue 53, Pages 7258-7261

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc08599g

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Funding

  1. DFG [STA1195/2-1]
  2. Institutional Strategy of the University of Bremen - German Excellence Initiative

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We present the synthesis of a B-N analogue of polystyrene, poly(N-methyl-B-vinylazaborine) in high molecular weight (M-W = 24.9 kDa). Furthermore, it was possible to prepare a copolymer with the C-C analogue. A thorough comparison between the polymers by NMR spectroscopy, TGA, DSC and GPC showed significant differences between these polymers.

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