Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 12, Issue 12, Pages 1305-1308Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201700471
Keywords
C-C coupling; enantioselective synthesis; hydroxycarbazoles; sorazolons; vanadium
Categories
Funding
- JSPS KAKENHI [JP16K08163, JP16H01152, JP17H05373]
- JST Advance Catalytic Transformation Program for Carbon Utilization (ACT-C) [JPMJCR12YK]
- Grants-in-Aid for Scientific Research [17H05373, 16K08163, 16H01152] Funding Source: KAKEN
Ask authors/readers for more resources
Short syntheses of 4-deoxycarbazomycin B and sorazolon E were established through the condensation of cyclohexanone and commercially available 4-methoxy-2,3-dimethylaniline, followed by Pd-II-catalyzed dehydrogenative aromatization/intramolecular C-C bond coupling and deprotection. A chiral dinuclear vanadium complex (R-a,S,S)-6 mediated the enantioselective oxidative coupling of sorazolon E, affording (+)-sorazolon E2 in good enantioselectivity.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
