Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 29, Pages 8412-8416Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201611254
Keywords
carbonylation; heterogeneous catalysis; MOFs; rhodium complexes; structure elucidation
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Funding
- Australian Research Council [DP160103234]
- JSPS/AAS
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Single-crystal X-ray crystallography is employed to characterize the reaction species of a full catalytic carbonylation cycle within a Mn-II-based metal-organic framework (MOF) material. The structural insights explain why the Rh metalated MOF is catalytically competent toward the carbonylation of MeBr but only affords stoichiometric turn-over in the case of Me-I. This work highlights the capability of MOFs to act as platform materials for studying single-site catalysis in heterogeneous systems.
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