Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 29, Pages 8568-8572Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201608589
Keywords
microwave chemistry; polyoxometalates; solution dynamics; spectroscopy; structural reorganization
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Funding
- ARC [DP110105530, DP130100483, DE140100550, DP150101388, DE130100615]
- Australian Research Council [DE130100615, DE140100550] Funding Source: Australian Research Council
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We report a new approach for the synthesis of heterohexa- and heterodecametalates via the use of nonaqueous, microwave-assisted reaction conditions. The two novel molybdovanadates have been isolated and characterized in the solid and solution states using single-crystal X-ray diffraction, FT-IR, UV/Vis, multinuclear NMR spectroscopy, and ESI-MS. The relative stabilities of the possible structural isomers were probed using dispersion-corrected DFT calculations for both polyoxometalate systems.
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