Journal
CHEMICAL REVIEWS
Volume 117, Issue 13, Pages 8864-8907Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemrev.6b00516
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Funding
- NSFC [21431008, 21332001, u1505242, 21302220]
- CAS/SAFEA International Partnership Program for Creative Research Teams
- State Key Laboratory of Structural Chemistry [20150009]
- Chongqing Natural Science Foundation [cstc2016jcyjA0008]
- Sun Yat-sen University
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C-H bond activation and decarboxylation are two significant processes in organic synthesis. The combination of these processes provides a novel synthetic strategy, that is, decarboxylative C-H bond functionalization. Considerable attention has been focused on such an active research field. This review offers an overview of the utility of decarboxylative C-H bond functionalization in the synthesis of various organic compounds, such as styrenes, chalcones, biaryls, and heterocycles, covering most of the recent advances of the decarboxylative functionalization of Csp-H, Csp(2)-H, and Csp(3)-H bonds, as well as their scopes, limitations, practical applications, and synthetic potentials.
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