4.7 Article

Reinforcing the corrosion protection property of epoxy coating by using graphene oxide-poly(urea-formaldehyde) composites

Journal

CORROSION SCIENCE
Volume 123, Issue -, Pages 267-277

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2017.04.019

Keywords

Graphene oxide; Urea-formaldehyde resin; Epoxy coatings; Barrier performance; Corrosion protection property

Funding

  1. International S & T Cooperation Project of China (ISTCP) [2014DFR50560]
  2. National Key Research and Development Plan
  3. Ministry of Science and Technology China [2016YFB0300604]
  4. Fundamental Research Funds for the Central Universities [HEUCFZ1502]

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A new type of modified graphene oxide (GO) coating was prepared by anchoring a prepolymer of urea-formaldehyde (UF) resin onto GO sheets through in situ polycondensation. The modified GO sheets were characterized by scanning electron microscopy, transmission electron microscopy, X-ray diffraction experiment, Fourier transforms infrared spectroscopy, sedimentation test, and electrochemical impedance spectroscopy. One major finding was that the superior compatibility of OF resin with epoxy resin retained the high dispersion of modified GO sheets in polymer matrix. Results further revealed that the modified GO sheets significantly reinforced the corrosion protection property of epoxy coatings on carbon steel substrate.

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