Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 53, Pages 7318-7321Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc03095a
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Funding
- Impulsing Paradigm Change through Disruptive Technologies Program (ImPACT)
- JST ERATO Grant, Japan [JPMJER1602]
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Polypeptides containing 2-aminoisobutyric acid (Aib) units as an unnatural amino acid residue were synthesized by papain-catalyzed chemoenzymatic polymerization of a tripeptide ethyl ester L-Ala-Aib-L-Ala-OEt in an aqueous medium. The Aib-containing polypeptide adopted an alpha-helix conformation in both the solid and solution phases, which was induced by the periodic Aib residue.
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