Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 53, Pages 7278-7281Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc01805c
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Funding
- Polish National Centre for Research and Development [LIDER 024/391/L-5/13/NCBR/2014]
- National Science Center [2015/18/E/ST5/00188, 2016/21/B/ST5/00175]
- EC through the Marie Curie ETN project iSwitch [642196]
- Labex project CSC within the Investissement d'Avenir program [ANR-10-LABX-0026 CSC, ANR-10-IDEX-0002-02]
- International Center for Frontier Research in Chemistry (icFRC)
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The functionalization of a spherical Keplerate-type polyoxometalate {Mo72V30} with a cationic azobenzene surfactant has been achieved through ionic self-assembly. The photoisomerisation reaction of this complex, which emerges in a light-triggered aggregation-disaggregation process, has been followed by H-1 NMR spectroscopy, dynamic light scattering, absorption spectroscopy and scanning electron microscopy analyses.
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