Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 53, Pages 7322-7324Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc02356a
Keywords
-
Categories
Funding
- Office of Naval Research Young Investigator Award [N00014-16-1-2917]
Ask authors/readers for more resources
We present the first ferromagnetically-coupled Er3+ complex with linked, high-anisotropy Er-COT (COT2- = cyclooctatetraene dianion) subunits. The dinuclear complex, [Er(mu(2)-Cl)(COT)(THF)](2), demonstrates single-molecule magnetism with a single, zero-field magnetization relaxation barrier of U-eff = 113 cm(-1). This system offers evidence that anisotropy can be preserved in the presence of ferromagnetic linking of the Er-COT subunits, providing a rational means to build strong molecular magnets of tunable dimensionality.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available