A Variable Mass Meso-Model for the Mechanical and Water-Expelled Behaviors of PVA Hydrogel in Compression

Static uniaxial compressive experiments were conducted to study the mechanical behaviors of polyvinyl alcohol (PVA) hydrogels in ambient conditions. It was found that water is expelled during the compression of hydrogels that have high water contents. It means hydrogels may be a mass variable under the compression. In order to depict the mechanical properties intrinsically, a variable mass model with meso-scale cells was proposed to simulate PVA hydrogels. In the model, there are uniform cells with frames of polymer fibers and water, and a virtue membrane designed to wrap up the boundary of the model. The model not only depicts the behaviors of the compressive mechanics and the expelled water, but also explains the nonlinear stress-strain relation of PVA hydrogels and why the hydrogels with high water content demonstrate a modulus considerably lower than the bulk modulus of water.