Journal
DALTON TRANSACTIONS
Volume 46, Issue 25, Pages 8190-8197Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7dt00836h
Keywords
-
Categories
Funding
- National Science Foundation of China [21531002, 21374019]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT-15R12]
- Shanghai Science Technology Committee [13JC1400600, 16ZD2270100]
Ask authors/readers for more resources
Functional metal bis(1,3,5-triazapentadienato) units [M(tap)(2)] (M = Ni-II/Pd-II) and pyrene groups were introduced as central units of three tetradentate tetrapyridyl-substituted ligands, with which seven half-sandwich organometallic complexes were controllably synthesized. The multi-centered hybrid products constructed from the two [M(tap)(2)] units revealed delocalized pi-bonding environments. The products were characterized by proton NMR and IR spectroscopy, elemental analyses and electrospray ionization (ESI) mass spectrometry. The molecular structures of four of the products were determined by X-ray diffraction analysis, revealing their octanuclear structures.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available