Journal
DALTON TRANSACTIONS
Volume 46, Issue 25, Pages 8167-8179Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7dt01159h
Keywords
-
Categories
Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan [JPH03782, JPK05444]
- JSPS KAKENHI [2408, JP24109011]
- Grants-in-Aid for Scientific Research [15K05444, 15H03782] Funding Source: KAKEN
Ask authors/readers for more resources
A base-free iron germylene complex Cp*(CO)(H)Fe=GeH{C(SiMe3)(3)} (1) was synthesised by abstraction of pyridine from a germyl complex Cp*(CO)(py)FeGeH2{C(SiMe3)(3)} (2), which was prepared by treatment of Cp*Fe(CO)(py)(Me) with H3GeC(SiMe3)(3). X-ray crystallographic analysis revealed that 1 has an Fe-Ge bond that is the shortest among those ever reported. Reactivity of 1 toward several polar unsaturated organic compounds was investigated. Complex 1 underwent stoichiometric hydrogermylation of carbonyl compounds such as ketones, aldehydes and isocyanates (RNCO) at room temperature. In contrast, the reactions of 1 with isothiocyanates (RNCS) resulted in clean cleavage of the CvS double bonds.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available