Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 23, Issue 40, Pages 9517-9524Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201700881
Keywords
Co9S8; electrochemistry; lithium-ion batteries; metal-organic frameworks; nanoparticles
Categories
Funding
- National Natural Science Foundation of China [NSFC 21171007, 21671005]
- Programs for Science and Technology Development of Anhui Province [1501021019]
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Co9S8 is considered a promising candidate as the anode material in lithium-ion batteries (LIBs) because of its remarkable electrical conductivity, high theoretical capacity, and low cost. However, the practical application of Co9S8 is greatly restricted because of its poor cycling stability and rate performance, which result mainly from the large volume expansion and dissolution of the polysulfide intermediates during the charge/discharge process. In this report, Co9S8 embedded in N-rich carbon hollow spheres are successfully designed and synthesized through an in situ pyrolysis and sulfurization process, employing the well-known ZIF-67 as the precursor and ethanethiol as the sulfur source. shell exhibit excellent lithium storage properties at a high charge/discharge rate. A discharge capacity of 784 mAhg(-1) is obtained upon battery testing at a current density of 1 C (544 mAg(-1)). Even upon cycling at a current density of 4 C, the as-prepared Co9S8/N-C can still deliver a discharge capacity of 518 mAhg(-1). The excellent battery performance can be attributed to the hollow structure as well as the Nrich carbon encapsulation. Moreover, this metal-organic framework sulfurization route also shows good generality for the synthesis of other metal sulfide-carbon composites such as ZnS/N-C and Cu2S/C.
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