Journal
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
Volume 88, Issue 3-4, Pages 247-252Publisher
SPRINGER
DOI: 10.1007/s10847-017-0723-7
Keywords
Supramolecular; Anions; Cucurbituril; Fluorescence; Framework
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Funding
- National Natural Science Foundation of China [21003123, 21373042]
- Fundamental Research Funds for the Central Universities
- National Natural Science Foundation of China [21003123, 21373042]
- Fundamental Research Funds for the Central Universities
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By linkage of 1,5-naphthalenedisulfonate (1,5-NDS) anion fluorophore, 3D cucurbit[7]uril (CB[7]) framework has been constructed. The maximum solid-state fluorescence wavelength of the CB[7] framework exhibits blue-shift from 406 to 340 nm in comparison with that of 1,5-NDS, which was ascribed to increased excited energy from 0.10 to 0.13 eV according to theoretical calculations.
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