Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 29, Pages 8559-8563Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201703147
Keywords
azides; beryllium; crystal structures; main group elements; quantum-chemical calculations
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Funding
- Fonds der Chemischen Industrie (FCI)
- University of Duisburg-Essen
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[Ph4P](2)[Be(N-3)(4)] (1) and [PNP](2)[Be(N-3)(4)] (2; PNP= Ph3PNPPh3) were synthesized by reacting Be(N-3)(2) with [Ph4P]N-3 and [PNP]N-3. Compound 1 represents the first structurally characterized homoleptic beryllium azide. The electronic structure and bonding situation in the tetraazidoberyllate dianion [Be(N-3)(4)](2-) were investigated by quantum-chemical calculations (NPA, ELF, LOL).
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