Journal
CATALYSIS SCIENCE & TECHNOLOGY
Volume 7, Issue 1, Pages 47-50Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cy01962e
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Funding
- Accelerated Innovation Research Initiative Turning Top Science and Ideas into High-Impact Values (ACCEL) program of the Japan Science and Technology Agency (JST)
- Japan Society for the Promotion of Science (JSPS) [15H04183]
- Grants-in-Aid for Scientific Research [15H04183] Funding Source: KAKEN
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Using kinetic analysis, we demonstrate that the rate-determining step for ammonia synthesis over Ru catalysts supported by electrides, such as [Ca24Al28O64](4+)(e(-))(4) and Ca2N:e(-), is not the N-2 dissociation step but the subsequent surface reactions of N and H adatoms, in which case the Langmuir-Hinshelwood model should be used to describe the kinetics.
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