Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 32, Pages 9577-9581Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201705641
Keywords
asymmetric catalysis; C-H activation; dihydropyrroles; domino reactions; Narasaka-Heck reactions
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Funding
- EPFL (Switzerland)
- Swiss National Science Foundation (SNSF)
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A palladium-catalyzed reaction of gamma,delta-unsaturated oxime esters with oxadiazoles afforded dihydropyrroles in good to excellent yields through an intramolecular iminopalladation/intermolecular direct heteroarene C-H alkylation cascade. This unprecedented iminoarylation of alkenes was subsequently realized in an enantioselective manner in the presence of a chiral bidentate phosphine ligand (Synphos).
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