Journal
ARABIAN JOURNAL OF CHEMISTRY
Volume 10, Issue 6, Pages 761-768Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.arabjc.2015.11.012
Keywords
Azo-imine ligand; Complex; Thermal; Catalysis
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Funding
- K. Maras Sutcu Imam University Research Projects Coordination Unit
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This work explains the synthesis of a new azo-Schiff base compound, derived from condensation between N-ethylcarbazole-3-carbaldehyde and 1,3-diaminopropane, followed by azo coupling reaction with the diazonium salt of 2-amino-4-methyl phenol. The newly synthesized azoSchiff base was further reacted with the acetate salts of Copper, Cobalt and Nickel to give three coordination compounds. All synthesized compounds have been characterized through spectral analysis. The coordination compounds have been examined for their thermal and catalytic features. Good and moderate yields were obtained for the oxidation of styrene and cyclohexene. Thermal features of the ligand and its complexes have been explained and the results obtained have supported the proposed structures. (C) 2015 The Authors. Production and hosting by Elsevier B.V. on behalf of King Saud University.
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