Journal
ADVANCED ENERGY MATERIALS
Volume 8, Issue 5, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201701674
Keywords
coherence length; morphology; polymer solar cells; small molecular acceptor; X-ray scattering
Categories
Funding
- National Basic Research Program of China (973 Program) [2013CB834701, 2014CB643501]
- Hong Kong Research Grants Council [T23-407/13 N, N_HKUST623/13, 16305915, 16322416, 606012]
- HK JEBN Limited, HKUST president's office [FP201]
- National Science Foundation of China [21374090]
- Hong Kong Innovation and Technology Commission [ITC-CNERC14SC01, ITS/083/15]
- ONR [N000141512322]
- Research Opportunity Initiative (ROI) Grant of the University of North Carolina General Administration
- Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy [DE-AC02-05CH11231]
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Nonfullerene polymer solar cells (PSCs) based on polymer donors and non-fullerene small molecular acceptors (SMAs) have recently attracted considerable attention. Although much of the progress is driven by the development of novel SMAs, the donor polymer also plays an important role in achieving efficient nonfullerene PSCs. However, it is far from clear how the polymer donor choice influences the morphology and performance of the SMAs and the nonfullerene blends. In addition, it is challenging to carry out quantitative analysis of the morphology of polymer: SMA blends, due to the low material contrast and overlapping scattering features of the p-p stacking between the two organic components. Here, a series of nonfullerene blends is studied based on ITIC-Th blended with five different donor polymers. Through quantitative morphology analysis, the (010) coherence length of the SMA is characterized and a positive correlation between the coherence length of the SMA and the device fill factor (FF) is established. The study reveals that the donor polymer can significantly change the molecular ordering of the SMA and thus improve the electron mobility and domain purity of the blend, which has an overall positive effect that leads to the enhanced device FF for nonfullerene PSCs.
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