Journal
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
Volume 13, Issue -, Pages 1463-1469Publisher
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.13.144
Keywords
aryldiazonium salts; borylation; eosin Y; mechanochemistry; photocatalysis
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Funding
- RWTH Aachen University through RWTH - Excellence Initiative of the German federal and state governments [StUpPD_221-16]
- RWTH Aachen University
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Merging of photo- and mechanochemical activation permitted studying the role of eosin Y in the borylation of aryldiazonium salts in a ball mill. Simultaneous neat grinding/irradiation of the reactants and the photocatalyst led to the formation of boronates in a molten state. On the other hand, the catalyst-free liquid-assisted grinding/irradiation reaction also led to product formation, featuring a direct photolysis pathway facilitated by substrate-solvent charge-transfer complex formation.
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