4.7 Article

Transforming a chemically labile [2+3] imine cage into a robust carbamate cage

Journal

CHEMICAL COMMUNICATIONS
Volume 53, Issue 61, Pages 8616-8619

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc03677a

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Funding

  1. DFG [MA4061-4/2, SFB 1249]
  2. China Scholarship Council (CSC)
  3. BMBF [136W0044]

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The synthesis of a highly acid and base-stable shape-persistent porous carbamate cage is presented. This cage is stable even in hot (100 degrees C) 1 M hydrochloric acid (pH = 0) or in concentrated hydrochloric acid ( pH = -1) at room temperature without decomposition.

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