Journal
CRYSTENGCOMM
Volume 19, Issue 29, Pages 4137-4141Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ce00224f
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Funding
- European Union's Horizon research and innovation programme under the Marie Sklodowska-Curie [641887]
- Fonds der chemischen Industrie (Liebig fellowship)
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Tailoring defects in metal-organic frameworks is important for enhancing sorption and reaction properties. Defects in UiO-66 have been characterized for the first time by using water adsorption measurements. We found that the defect-induced hydrophilicity, quantitatively expressed by the Henry constant and the saturation water uptake, correlates well with the catalytic performance in the cyanosilylation of benzaldehyde.
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