4.7 Article

Base free transfer hydrogenation using a covalent triazine framework based catalyst

Journal

CRYSTENGCOMM
Volume 19, Issue 29, Pages 4166-4170

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ce00561j

Keywords

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Funding

  1. Generalitat Valenciana (projects Consolider-Ingenio MULTICAT) [AICO/2015/065]
  2. Spanish Ministry of Economy and Competitiveness (MINECO) [SEV20120267]
  3. Spanish Ministry of Science and Innovation (MICINN) [MAT2014-52085-C2-1-P]
  4. European Union's Horizon research and innovation programme under the Marie Sklodowska-Curie grant [641887]
  5. European Union Seventh Framework Programme (FP7) [309701]

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Isomerisation of allylic alcohols to saturated ketones can be efficiently catalysed by a heterogeneous molecular system resulting from (IrCp)-Cp-III* anchoring to a covalent triazine framework. The obtained catalysts are active, selective, and fully recyclable.

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