C-F/C-H Functionalization by Manganese(I) Catalysis: Expedient (Per)Fluoro-Allylations and Alkenylations

C-F/C-H functionalizations proved to be viable within a versatile manganese(I) catalysis manifold. Thus, a wealth of fluorinated alkenes were employed in C-F/C-H functionalizations through facile C-H activation. The robust nature of the manganese(I) catalysis regime was among others reflected by the first C-F/C-H activation with perfluoroalkenes as well as racemization-free C-H functionalizations on imines, amino acids, and peptides.