Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 23, Issue 42, Pages 10013-10016Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201702028
Keywords
alkynes; copper; fluorine; selenium; trifluoromethylselenolation
Categories
Funding
- la Region Rhone Alpes
- CNRS
- French Fluorine Network
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The successful perfluoroalkylselenolation of alkynyl copper(I) compounds is described herein. The reaction occurs under oxidant free conditions at room temperature. This convenient one-pot procedure is based on the in situ generation of trifluoromethylselenyl chlorides. The developed system shows high functional group tolerance and also promotes the employment of fluoroalkyl derivatives.
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