Journal
ACS CATALYSIS
Volume 7, Issue 10, Pages 7120-7125Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.7b02754
Keywords
silylation; peroxidation; alkenes; radicals; silanes
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Funding
- National Natural Science Foundation of China [21672198]
- State Key Program of National Natural Science Foundation of China [21432009]
- State Key Laboratory of Elemento-organic Chemistry Nankai University [201620]
- Open Project of Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University [2017110]
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A synthetic method of copper-catalyzed silylperoxidation of alpha,beta-unsaturated carbonyl compounds and conjugated enynes has been developed. The realization of silylperoxidation of the carbon carbon double bond permits direct access to silicon-containing peroxy products in moderate to good yields. Furthermore, this protocol distinguishes itself by operational simplicity and exhibiting good tolerance of a wide scope of functional groups. This strategy provides an efficient approach to the 1,2-difunctionalization of alpha,beta-unsaturated carbonyl compounds and conjugated enynes.
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