Journal
ACS CATALYSIS
Volume 7, Issue 6, Pages 4126-4130Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.7b01120
Keywords
photoredox; vinylation; allylation; trifluoroborate; electrochemistry
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Funding
- European Union [PCIG13-GA-2013-631556]
- EPSRC [4500284613]
- AstraZeneca
- Marie Curie Actions [703238]
- Department of Chemistry, King Faisal University, Saudi Arabia
- EPSRC [EP/P004997/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/P004997/1, 1781625] Funding Source: researchfish
- Marie Curie Actions (MSCA) [703238] Funding Source: Marie Curie Actions (MSCA)
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Visible-light photoredox catalysis enables the vinylation and allylation of electrophilic radicals with readily available potassium trifluoroborate reagents. The processes show good functional group compatibility, and mechanistic and computational studies have elucidated some of the aspects associated with the key radical addition step.
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