Journal
ACS CATALYSIS
Volume 7, Issue 3, Pages 1543-1553Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.6b02767
Keywords
hydrosilylation; heterogeneous catalysts; Pd-Au alloy; silyl enol ether; vinylsilane; X-ray absorption spectroscopy
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Funding
- Program for Element Strategy Initiative for Catalysts & Batteries (ESICB)
- Platform for Technology and Industry [26820353]
- Grants-in-Aid for Scientific Research [26289305, 17H06443, 17H03459] Funding Source: KAKEN
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Supported Pd-Au alloy catalysts were developed for the highly efficient and selective hydrosilylation of alpha,beta-unsaturated ketones and alkynes. The Pd/Au atomic ratio of the Pd-Au alloy and the supporting material affected the catalytic activity, and supported Pd-Au alloy nanoparticles with a low Pd/Au atomic ratio functioned as highly active heterogeneous catalysts under mild reaction conditions. Structural characterization of supported Pd-Au alloy catalysts by X-ray diffraction, X-ray absorption spectroscopy (XAS), and transmission electron microscopy revealed the formation of random Pd-Au alloy nanoparticles with a uniform size of around 3 nm on the support. Furthermore, XAS and X-ray photoelectron spectroscopy elucidated the charge transfer from Pd to Au and the formation of isolated single Pd atoms in random Pd Au alloys with a low Pd/Au ratio, which enabled efficient hydrosilylation of a variety of substrates under mild reaction conditions.
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