Journal
ACS CATALYSIS
Volume 8, Issue 1, Pages 144-147Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.7b03366
Keywords
alkynes; aromaticity; multinuclear catalysis; cascades; diastereoselectivity
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Funding
- MIUR
- UniPR
- UPCM
- CNRS
- SIR Project AROMA-TriP [RBSI14NKFL]
- FIL Project RADICAT
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Highly symmetric all-metal aromatic Pd-3(+) complexes can catalyze the cycloisomerization of terminal 1,6-enynes and internal dienynes under mild conditions. Modification of substrates dictates the mechanism and steers the reaction toward different polycyclic frameworks, enabling the development of complex cascades. The reactivity of Pd(4/3) complexes is complementary to that of mononuclear Pd(0) and Pd(II) ones.
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