Journal
ACS CATALYSIS
Volume 7, Issue 4, Pages 2720-2724Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.7b00053
Keywords
nitrogen-functionalization; porous carbon; heterogeneous catalysis; palladium; formic acid; dehydrogenation
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Funding
- International Joint Research Program for Innovative Energy Technology of the Ministry of Economy, Trade, and Industry (METI)
- Nanotechnology Platform Program (Molecule and Material Synthesis) of the Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan
- Grants-in-Aid for Scientific Research [17K06917] Funding Source: KAKEN
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Highly dispersed palladium nanoclusters (Pd NCs) immobilized by a nitrogen (N)-functionalized porous carbon support (N-MSC-30) are synthesized by a wet chemical reduction method, wherein the N-MSC-30 prepared by a tandem low temperature heat-treatment approach proved to be a distinct support for stabilizing the Pd NCs. The prepared Pd/N-MSC-30 shows extremely high catalytic activity and recyclability for the dehydrogenation of formic acid (FA), affording the highest turnover frequency (TOF = 8414 h(-1)) at 333 K, which is much higher than that of the Pd catalyst supported on the N-MSC-30 prepared via a one-step process. This tandem heat treatment strategy provides a facile and effective synthetic methodology to immobilize ultrafine metal NPs on N-functionalized carbon materials, which have tremendous application prospects in various catalytic fields.
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