Journal
ACS CATALYSIS
Volume 7, Issue 2, Pages 1077-1086Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.6b02715
Keywords
carbon dioxide; methylation; reduction; catalysis; amines
Categories
Funding
- state of Mecklenburg-Vorpommern
- BMBF
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Developing new synthetic approaches for benign CO2 utilization is of current interest. In this respect, reductive allcylations using N- or C-based nucleophiles to give the corresponding methyl amines and (hetero)arenes are investigated intensively. Crucial points for such benign methylations are the choice of suitable homogeneous or heterogeneous catalyst systems. In this article, selective activation of the substrates and the use of acidic cocatalysts are highlighted.
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