Journal
ACS CATALYSIS
Volume 7, Issue 4, Pages 2786-2790Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.6b03259
Keywords
water addition; aldehyde-water shift; acceptorless dehydrogenation; carboxylic acids; naphthyridine
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Funding
- DST
- DAE
- CSIR, India
- UGC, India
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A [RuH(CO)(py-NP)(PPh3)(2)]Cl (1) catalyst is found to be effective for catalytic transformation of primary alcohols, including amino alcohols, to the corresponding carboxylic acid salts and two molecules of hydrogen with alkaline water. The reaction proceeds via acceptorless dehydrogenation of alcohol, followed by a fast hydroxide/water attack to the metal-bound aldehyde. A pyridyl-type nitrogen in the ligand architecture seems to accelerate the reaction.
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