Journal
ACS CATALYSIS
Volume 7, Issue 12, Pages 8454-8459Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.7b02811
Keywords
zinc; hydrosilylation; hydroboration; N-heterocycles; DFT calculations
Categories
Funding
- American Chemical Society [53349-ND3]
- NSERC [2014-04410]
Ask authors/readers for more resources
The zinc hydride NacNacZnH (2) (NacNac = [Ar'NC(Me)CHC(Me)NAr'](-), Ar' = 2,6-Me2C6H3) catalyzes regioselective hydrosilylation and hydroboration of pyridines, including the hydroboration of phenanthroline. Mechanistic studies of hydrosilylation, including labeling, kinetic analysis, and density functional theory calculations, suggest the possibility of a reaction pathway based on hydride transfer from an out-of-sphere activated silane.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
