Journal
ACS CATALYSIS
Volume 7, Issue 8, Pages 5357-5362Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.7b01669
Keywords
sulfinates; photocatalysis; alkylation; benzylation; iridium catalyst
Categories
Funding
- Spanish MINECO
- Bologna University
- Fondazione Del Monte
- SLAMM project
- CNR
- CNR-CONICET
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Alkyl radicals are obtained by photocatalytic oxidation of readily prepared or commercially available zinc sulfinates. The convenient benzylation and alkylation of a variety of electron-poor olefins triggered by the iridium(III) complex 6 Ir[dF(CF3)-ppy](2)(dtbbpy)PF6 as photocatalyst is described. Moreover, it is shown that zinc sulfinates can be used for facile nonradical sulfonylation reactions with highly electrophilic Michael acceptors.
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