Journal
APPLIED MATERIALS TODAY
Volume 7, Issue -, Pages 82-90Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apmt.2017.01.005
Keywords
Oxygen reduction reaction; Hemoglobin electrocatalysis; Cyclic voltammetry; Nafion films
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Funding
- European Research Council (ERC) [320403]
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We describe experiments which elucidate the reaction mechanism of electrochemical oxygen reduction reaction (ORR) on a glassy carbon electrode modified with hemoglobin in an aqueous environment but with the hemoglobin physically separated from the electrode by a porous Nafion layer. Catalytic amplification of the current signal from the reduction of oxygen in a first electron transfer step is observed in the presence of hemoglobin immobilized within a Nafion coating. An overall four electron ORR mechanismis inferred and validated. (C) 2017 Elsevier Ltd. All rights reserved.
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