4.1 Article

NANOSCALE CHARACTERIZATION OF Au2Te GRAINS FROM THE SANDAOWANZI GOLD DEPOSIT, NORTHEAST CHINA

Journal

CANADIAN MINERALOGIST
Volume 55, Issue 2, Pages 181-194

Publisher

MINERALOGICAL ASSOC CANADA
DOI: 10.3749/canmin.1600077

Keywords

Au2Te grain; nanographic texture; mixture; decomposition or breakdown; Turing pattern; Sandaowanzi; China

Categories

Funding

  1. Major Basic Research Program of the People's Republic of China [2014CB440903]
  2. Specialized Research Fund for the National Natural Science Foundation of China [41573036, 40973035]
  3. Doctoral Program of Higher Education [20130022110001]
  4. Key Program of the National Natural Science Foundation of China [41030423]
  5. MOST Special Fund from the State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences
  6. 111 Project under the Ministry of Education [B07011]
  7. State Administration of Foreign Experts Affairs, China [B07011]

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Au2Te has previously been reported as a new mineral, although without adequate mineralogical data. Examination of Au2Te grains from the Sandaowanzi gold deposit, utilizing optical microscope, EPMA, SEM backscattered electron, and X-ray images revealed an apparently homogeneous composition leading to its examination as a possible new mineral. However, high resolution SEM, TEM, and micro-zone XRD analyses demonstrate that the Au2Te phase gives a false stoichiometry and is not a new mineral species, but a mixture of native gold and calaverite with a nanographic texture that is highly comparable to that of the Turing pattern. This finding implies that the nanographic textures of Au2Te composed of alternating growth layers of native gold (Au) and calaverite (AuTe2) are attributable to decomposition or breakdown of the previous metastable phases during cooling.

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