Journal
CORROSION SCIENCE
Volume 124, Issue -, Pages 10-24Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2017.04.010
Keywords
Metal matrix composites; Stainless steel; AFM; EIS; Acid corrosion; Passive films
Funding
- DOE Nuclear Energy University Program [DE-NE-IL-UIC-0203-02]
- U.S. Department of Energy Office of Science [DE-ACO2-06CH11357]
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The effects of added Ru and Pd on the microstructure and electrochemical behaviour of a composite material made by melting those metals with AISI 410 stainless steel, Zr, Mo, and lanthanide oxides were assessed using electrochemical and microscopic methods The lanthanide oxides reacted with Zr to form durable lanthanide zirconates and Mo alloyed with steel to form FeMoCr intermetallics. The noble metals alloyed with the steel to provide solid solution strengthening and inhibit carbide/nitride formation. A passive film formed during electrochemical tests in acidic NaCl solution, but became less effective as corrosion progressed and regions over the intermetallics eventually failed.
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